Xa kuziwa kwinkqubo yokumisela ukuba yeyiphi isinyithi eya kucwecwa kuqala ekuphenduleni kokunciphisa, kukho izinto ezininzi ekufuneka ziqwalaselwe. Enye into ephambili kukuncitshiswa okunokwenzeka (okanye amandla omgangatho we-electrodeposition) yentsimbi evavanywayo. La manqanaba anokuthi ahluke ngokuxhomekeke kwiqondo lokushisa kunye nezinye iimeko zokusingqongileyo.
(Indlela yokumisela ukuba yeyiphi iMetal eya kuPlayithwa kuqala ngokuSekwe kuNciphiso lweZakhono)
Ukumisela amandla okunciphisa isinyithi, ungasebenzisa iindlela ezahlukeneyo ezifana nendlela elula yokutshaja isinyithi nge-asidi okanye ngokusebenzisa i-Mott-Hall effect.. Nangona kunjalo, kwiimeko ezininzi, ezi ndlela azithembekanga ngokwaneleyo ukulinganisa ngokuchanekileyo amandla okunciphisa. Kunoko, kunokufuneka usebenzise ubuchule obuphezulu obufana nohlalutyo lweekhemikhali okanye i-spectroscopy.
Enye indlela yokumisela amandla okunciphisa isinyithi kukulinganiswa kwe-electrochemical. Umlinganiselo we-electrochemical uquka ukuveza isinyithi kumbane onamandla, nto leyo eyenza ukuba isinyithi sihlawuliswe. Ngokulinganisa utshintsho kwintlawulo ngokuhamba kwexesha, unako ukubala amandla okunciphisa isinyithi.
Enye indlela yokumisela amandla okunciphisa isinyithi ngokusebenzisa i-spectroscopy. I-Spectroscopy ibandakanya ukuhlalutya ukufunxa okanye ukuphuma kokukhanya okukhutshwa yintsimbi.. I-absorbence okanye i-spectrum ephumayo inokubonelela ngolwazi malunga nesakhiwo sombane kunye nokusabalalisa kwee-electron ngaphakathi kwesinyithi, enokunceda ukumisela amandla ayo okunciphisa.
Ukongeza kwikhono lokunciphisa, kufuneka kwakhona uqwalasele ezinye izinto ezinokuchaphazela izinga lokunciphisa isinyithi. Umzekelo, ukuxinwa kwe-arhente yokunciphisa, ubushushu, kunye nobukho bobunye ukungcola konke kunokuchaphazela izinga lokunciphisa kunye nemveliso yokugqibela eyenziwe.
(Indlela yokumisela ukuba yeyiphi iMetal eya kuPlayithwa kuqala ngokuSekwe kuNciphiso lweZakhono)
Kuko konke, xa umisela ukuba yeyiphi isinyithi esiza kuphuma kuqala kwi-reaction yokunciphisa, kubalulekile ukuqwalasela izinto ezahlukeneyo. Ngokukhetha ngononophelo ukusetwa kovavanyo olufanelekileyo kunye nendlela yokusebenza, unokufumana iziphumo ezichanekileyo nezithembekileyo. Ngezixhobo ezifanelekileyo kunye nobuchule, unokugqiba amandla okunciphisa nayiphi na isinyithi kwaye wenze izigqibo ezinolwazi malunga nokusetyenziswa kweso sinyithi kwinkqubo ethile.